Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers
نویسندگان
چکیده
منابع مشابه
Matrix-Isolated Infrared Absorption Spectrum of CH2IOO Radical.
The peroxyiodomethyl radical, CH2IOO, was generated in cryogenic matrices using tandem supersonic nozzles. One hyperthermal nozzle decomposes diiodomethane (CH2I2) to generate intense beams of CH2I radicals, while the second nozzle continuously deposits O2/argon (Ar) on the matrix at 10 K. The CH2I and O2 in the Ar matrix react to produce the target peroxy radical (CH2IOO). The absorption spect...
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15 صفحه اولInfrared identification of matrix isolated H2O.O2.
Theoretical studies of the H2O.O2 complex have been carried out over the past decade, but the complex has not previously been experimentally identified. We have assigned IR vibrations from an H2O.O2 complex in an inert rare gas matrix. This identification is based upon theoretical calculations and concentration dependent behavior of absorption bands observed upon co-deposition of H2O and O2 in ...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 1981
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.442648